Parameter Reference

CalciumCa

Calcium is the cation half of the CaCO₃ skeleton equation. The reef hobby fixates on this number, sometimes at the expense of alkalinity and magnesium. Below 380 ppm corals struggle; between 380–450 they grow well; above 500 you're courting precipitation. Most well-run reefs sit between 400–440 and rarely think about Ca specifically.

Target ranges

Beginner-safe380–450 ppm
Optimal (consensus)400–450 ppm
Triton method target420–440 mg/L
Natural seawater400–412 ppm

Why it matters

Coral, coralline algae, clams, and Halimeda all build calcium-carbonate skeletons. They consume Ca and alkalinity in roughly equimolar amounts (1:1 by ion count, ~1 ppm Ca per 0.14 dKH alk). This is why a tank that drops 1 dKH per day also drops about 5–6 ppm Ca per day. Dose them together or you create imbalance.

Ca is much slower-moving than Alk in terms of perception — alk swings 1 dKH look dramatic on a test kit but represent the same amount of total ion movement as a 7 ppm Ca change, which barely registers visually.

Symptoms of drift

Too low

Below 380 ppm: slow coral and coralline growth, weakened skeletons. Below 360 ppm corals, clams, and Halimeda all get progressively worse (Randy). Coralline algae stop spreading first — early visual indicator.

Too high

Above 500 ppm: precipitation risk, especially if alkalinity is also elevated. "Snowstorm" event if Ca and Alk doses overlap in time at high concentrations — the water turns cloudy white with CaCO₃ particulates.

Testing

Salifert Calcium and Red Sea Calcium Pro are the workhorse titration kits — 5 ppm resolution if you titrate slowly. Hanna HI758 Calcium Checker is faster but expensive per test. Test once a week alongside alkalinity. Drift is slow so weekly cadence is plenty unless you're commissioning new dosing.

FAQ

What if Ca is at 380 but Alk is at 11?
Don't dose Ca to chase up — raise Mg first if it's low, then bring Alk down to 9–10 over a few days, then let consumption pull both into balance. Force-dosing Ca at high Alk triggers precipitation.
Why doesn't pure CaCl₂ dosing work long-term?
Calcium chloride alone adds Ca²⁺ and 2 Cl⁻ for every dose. Long-term you build chloride imbalance. Pairing with NaHCO₃ (the alk side) gives you NaCl as the net residue — the salt your salt mix already contains. Water changes purge the small drift.

Sources & references

  1. 01
    Randy Holmes-Farley — Optimal Parameters for a Coral Reef Aquarium
    https://www.reef2reef.com/threads/optimal-parameters-for-a-coral-reef-aquarium-by-randy-holmes-farley.173563/
  2. 02
    Randy Holmes-Farley — A Homemade Two-Part Calcium and Alkalinity Additive System
    https://reefs.com/magazine/aquarium-chemistry-a-homemade-two-part-calcium-and-alkalinity-additive-system/
  3. 03
    Triton — CoreChem
    https://www.triton.de/en/products/corechem
  4. 04
    Global Seafood Alliance — Typical chemical characteristics of full-strength seawater
    https://www.globalseafood.org/advocate/typical-chemical-characteristics-of-full-strength-seawater/
  5. 05
    Red Sea — Foundation Complete Manual
    https://redseafish.com/wp-content/uploads/2020/11/24653_Manual-Foundation-Complete-GB-_v21a-WEB.pdf

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