Troubleshooting
Low alkalinity in a reef tank — diagnosis and fixes
Symptom: Alkalinity below 7 dKH. SPS tips losing color (often the first sign). pH unstable. Calcium also dropping.
Likely causes, ranked
1. Coral demand exceeds water-change replenishment
very commonDiagnosticTank has been growing well, alkalinity is dropping ~0.3 dKH per day or more. SPS adding visible growth (encrustation, polyp extension).
FixStart two-part dosing. Use the alkalinity dosing calculator to figure out daily dose. Begin at 50% of the calculated dose and increase weekly while testing alk + Ca.
2. Switched salt mix to a lower-alk brand
commonDiagnosticRecent switch from Red Sea Coral Pro (11.5 dKH) to a low-alk salt (e.g. Tropic Marin Pro Reef at 7.5 dKH). Alkalinity dropped after the second or third water change.
FixEither go back to the higher-alk salt OR start two-part to make up the gap. There's no wrong answer; just pick a target dKH and stick to it.
3. Calcium reactor effluent too slow or pH wrong
commonDiagnosticYou have a reactor but alk is dropping anyway. Check effluent pH (should be 6.5–6.8) and effluent drip rate. Bubble counter has slowed.
FixCalibrate the pH probe (annual minimum). Check CO₂ regulator output. Increase effluent flow until daily uptake matches your tank's consumption.
4. Magnesium too low
commonDiagnosticMg <1,200 ppm. Alk and Ca both drop faster than dosing can replace.
FixRaise Mg to 1,300–1,400 ppm before continuing alk/Ca dosing. Without adequate Mg, Ca and CO3 precipitate together as calcium carbonate, removing both at the same time.
5. Recent kalkwasser stop without alternative
less commonDiagnosticWere running kalk in top-off; switched to plain RODI. Alk dropped over 2–3 weeks.
FixResume kalk, OR start two-part to match the alk supply rate. Switching between methods requires bridging.
Common myths
ClaimRaising alkalinity quickly is fine if Ca and Mg are also high.
RealityCoral mucus production is alkalinity-shock-sensitive regardless of Ca/Mg. Stick to ≤1.4 dKH per day. Source: Holmes-Farley.
To raise alkalinity
DIY two-part is cheapest: baked baking soda + calcium chloride. Pre-mixed liquid two-part if you want zero prep. Test alk daily until you know your tank's daily uptake.
Arm & Hammer Baking Soda — 13.5 lb
Bake at 250°F for 1 hour to convert to soda ash. Cheapest alk source.
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BRS Pharma Sodium Bicarbonate (alkalinity component)
Pre-baked NaHCO₃ for Randy/BRS two-part. Skip the oven step.
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BRS Pharma Calcium Chloride (Ca component)
Anhydrous CaCl₂ for two-part dosing. Use Randy's recipe math.
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ESV B-Ionic Two-Part
Pre-mixed liquid two-part if you don't want to DIY.
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Salifert KH/Alkalinity test kit
The hobbyist standard for alkalinity testing.
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Related
Sources & references
- 01Randy Holmes-Farley — Alkalinityhttp://reefkeeping.com/issues/2002-02/rhf/feature/index.php
Last reviewed